The poorly defined “bioavailability” term was parameterized into three chemically defined exposure parameters, that can be measured by means of diffusive sampling techniques and that subsequently can be applied within the environmental risk assessment and management of chemicals and polluted sites. The three types of parameters are: 1. chemical activity, freely dissolved concentration or fugacity. These parameters quantify the potential of a chemical for spontaneous processes such as diffusion and partitioning. 2. accessibility, which describes the quantity of a chemical that is or can become available. It will always be operationally defined.3. diffusive conductivity that characterises the diffusive property of an exposure media for a specific analyte.